Research into the Investment Casting Process & Materials

The following are a collection of technical papers that have been produced by Remet to explore in detail the issues of relevance to the precision investment casting foundry.

Targeted to aid process and part engineers, Remet’s technical papers serve as a reference point for the investment casting technical community. Providing information on the research undertaken in both our North American and European laboratories, the below papers present studies into the advanced materials used within today’s modern investment casting foundry. In addition to this, there are also papers discussing the prevention of casting defects and practices of process control.

Many of the articles have been presented at various technical conference hosted by organisations such as the Investment Casting Institute, European Investment Caster’s Federation and the Japanese Foundry Society. If there is a specific paper you are looking for and cannot find please contact us.

 

Investment Casting Wax

UK9 – A Recent Development in Pattern Wax Formulation – Is There a New Paradigm?

Dr. Grant Bradley, April 2016

Presented at the 14th World Conference on Investment Casting.

Field trials and laboratory work are reported in this paper which describe the performance of a new family of wax formulations. The results from these trials demonstrate process improvements such as: drastic shortening of cycle times (Up to 90% in some cases); paste injection temperatures down to 50C (with improved energy efficiency and reduced cooling requirements); unfilled wax which exhibits equivalent shrinkage to filled material; elimination of chills with little compromise in dimensional performance; and exceeding process robustness. Results are presented for a number of part sizes and types injected across a range of injection machines. Dimensional, process control, cycle time, calorimetric and rheological data are included.

UK8 – Application of Dynamical Mechanical Analysis and Rheometry for Measuring Dwell Time in FastFrom Pattern Wax

Increasing Productivity through Shortening Dwell Times with FastForm®

The Remet FastForm® range of injectable waxes were designed to set up rapidly and are ideally suited for increasing productivity when injecting large patterns such as those found in precision investment cast pumps and valve bodies used in oil and gas industries. Initial results of DOE studies carried out with an MPI wax injector showed a marked decrease in cycle time while maintaining dimensional and surface finish quality comparable to standard wax. Establishing acceptable injection parameters for each wax injector often requires large number of samples to be injected. Thermophysical instrumentation offers methods independent of injection machine for characterizing these parameters. Differential scanning calorimetry (DSC) has been used to examine the crystallization and solidification of wax and wax components. DMA (Dynamic Mechanical Analysis) has been used to characterize solid shrinkage of wax. We have previously reported on the potential for controlled stress rheometry (CSR) and DMA as investigative tools to look at the viscoelastic properties of waxes across the solid/liquid phase boundary. These investigative approaches were correlated with results obtained with the MPI injector. This composite approach permits a potential user of pattern waxes such as FastForm® to quickly establish injection parameters from a reduced number of test injections.

UK4 – Kinetics vs Thermodynamics. How Equilibrium States are Established in Investment Casting Waxes

A New Method for Simulating Pattern Wax Behaviour During Injection

Bob Brown & Joe Stanco, 2012

Presented to the Investment Casting Institute at the 59th Annual Technical Conference by Dr. Grant Bradley.

In both the waxes and the slurries employed in investment casting, the control mechanisms involved in the contention between kinetically and thermodynamically driven processes are of joint scientific and practical interest. Particularly during the injection of a wax, the temperature the material experiences and changes in temperature profile during the injection process can have effects on the flow and dimensional characteristics of a wax. An understanding of these mechanisms allows strategies to be developed to improve control of the investment casting process and surface definition of wax patterns.

Controlled stress rheometry and dynamic mechanical analysis (DMA) have been employed to study the behaviour of waxes at the onset of congealing under flow conditions in an attempt to measure these effects. Characterization of the wax using controlled stress rheometry reveals phase changes that occur along with linear viscoelastic behaviour. Temperature modulated DMA allows for the investigation of reversible and non-reversible phenomena in the melting and crystallization region of waxes. Temperature modulated DMA also provides high sensitivity for small and slow changes in crystallinity, e.g. during re-crystallization. The combination of controlled stress rheometry and DMA yields an accurate simulation of the conditions an investment casting wax is exposed to during the injection process. This simulation is able to be extended including the period after injection when the wax is finding a new equilibrium in the tool, and over the longer term as the injected part relaxes.

Health and Safety Aspects of Investment Casting Waxes

Considerations for these Materials & their Use

 

Wax based blends are an essential part of the investment casting process.ƒ‚ They are complex mixtures of natural and synthetic organic compounds and, as such, can present a variety of health hazards if handled incorrectly.

In this paper, the author takes a detailed look at the health and safety aspects of investment casting waxes, focusing on the physical and chemical hazards these materials can present in the wax room and the correct handling and processing techniques that should be used to counter them.

Reference is made to current health and safety legislation, examining how it impacts on both the manufacturers and users of casting waxes

The Mechanical Properties of Investment Casting Waxes

Material Characterisation & Testing Methods to Determine Suitability

 

The mechanical properties of casting waxes play a vital part in the investment casting process. Wax patterns must be sufficiently tough to resist breakage during assembly and must not distort if dimensional tolerances are to be maintained. Equally, runner bars must not fracture or sag when assemblies are handled by robot dipping lines.

In this paper, the author describes a straightforward approach for characterising these mechanical properties. The method, based around a three point bending technique, uses inexpensive and readily available equipment to generate numerical and graphical information on wax properties such as toughness and flexibility.

The paper goes on to describe how this information is directly relevant to the efficient running of the wax room and the investment casting process in general. The paper contains many illustrations showing the equipment and techniques used as well as the results generated.

Successful Investment Casting of Titanium Alloys

Compiling a Successful Solution for Reactive Alloy Casting

 

The investment casting of titanium alloys is growing in importance and economic value. The reactive nature of these alloys forces the foundry to be more critical in selecting the key materials the pattern and runner waxes, and the primary and second coat binders, flours and stuccos used in the process.

This paper reviews Wax, Binder and Refractory options available to the investment caster, for titanium casting, this includes a discussion of the factors to be considered when making the selection.

Finally this paper provides system recommendations that will enable a foundry to begin investment casting of titanium alloys.

Water Soluble Cores for Investment Casting

Improving Surface Finish & Dimensional Consistency in the use of Cores

 

It is the intent of this paper to provide the foundry man with a broader understanding of soluble cores from a functionality stand point by reviewing their chemistry and analyzing their physical and chemical behavior in the foundry.

In addition, guidelines will be provided to enhance surface finish, dimensional consistency and dissolution characteristics that in turn could help generate a better pattern wax thus a better final casting.

An Overview of Rheology of Investment Casting Waxes

New Assesment Method Offering Greater Insight for Injection & Dewax Processes

 

Remet is evaluating a new method for assessing the rheological properties of its waxes on both a heating and cooling basis with the aim of providing a greater insight into wax performance under injection and dewax conditions. This paper describes the testing that has been done to date and provides interpretative comments regarding wax performance in the foundry.

Wax Characterisation

Wax Components & their Effect on the Investment Casting Process

 

Precision investment casting waxes are a complex blend of several different carefully selected ingredients.ƒ‚ Fillers, additives, resins, microcrystalline and paraffin waxes are used to develop the desired wax to meet the specific requirements of the investment caster.ƒ‚ The blend is then analyzed and the results are used to characterize the end product.ƒ‚ This paper will look at the various properties that are tested and evaluated.ƒ‚ The different properties of a wax will be explained in detail, with an emphasis on how each property influences the investment casting process.ƒ‚ In addition, the interaction that occurs at the wax/primary slurry interface will be discussed.

The Effect of Fillers on the Physical Properties of Investment Casting Waxes

A Study into the Volumetric Sinkage of an Injected Part

 

A large proportion of the investment casting waxes in current use contain fillers of one type or another.ƒ‚ In helping to control excessive pattern shrinkage and sinkage, these fillers facilitate the production of the large, complex and tightly dimensioned castings required in today’s markets.

In this paper, the author explores the effects these fillers have on the physical properties of the wax blends in which they are incorporated.

Four commonly used fillers are blended, at different levels, into a common base wax.ƒ‚ The resulting filled blends are laboratory tested for a variety of physical properties, including viscosity and volumetric expansion.ƒ‚ The “real world” performance of the blends is also evaluated by injecting them into a standard test piece and performing dimensional analysis on the resulting patterns.

The work shows that fillers play a vital role in controlling levels volumetric sinkage of injected parts and that they have a major influence on the basic physical properties of filled casting waxes.

Investment Casting Binder

Enhanced Binders for Improving Performance of Backup Coats in Precision Investment Casting Shells

Benefits of REMASOL® 3301 for Ceramic Shells with Complex Geometries

 

Researched and authored by Joseph Stanco, Manueal Guerra and Charles Matzek and presented by Dr. Grant Bradley at the ISIC-Tokyo 2013, this paper gives consideration to methods and materials that improve the critical backup ceramic shell coating.

Investment casting shells are subjected to various mechanical and thermal stresses during the different stages of the investment casting process. The backup portion of the shell system is critical in providing support to the facecoat while maintaining overall shell strength during dewaxing, firing, and metal pour without distortion or loss of dimensional stability. Colloidal silica binders often provide minimal green strength to allow the shell to survive dewaxing but do not have adequate permeability to promote gas transfer through the shell wall. They also typically produce shells with higher than needed hot strength.  Enhanced binders are engineered to provide a balance between increased green strength needed for dewaxing with sufficient hot strength for metal pouring and good gas flow. Studies of enhanced binder system, specifically, Remet’s REMASOL® ADBOND® 3301, were conducted and characterized for green, hot, and fired strengths along with dry times between dips and permeability. Results show that backups dipped in REMASOL ADBOND 3301 retained higher green strength to minimize distortion during shell build with improved permeability. Benefits of REMASOL ADBOND 3301 also include reduced dry times between dips to allow rapid building of shells with complex geometries that include cores, blind holes, and difficult to dry areas.

REMASOL® ADBOND® SP-3301 and LP-3301 Binders

A Faster Setting Investment Casting Binder

 

REMASOL® ADBOND® SP-3301 and LP-3301 are enhancements of the commercially successful REMASOL® ADBOND® BV binders to promote faster setting shell systems. These systems are particularly viable where parts contain deep pockets that are difficult to dry. Because it can be used at low silica concentrations it has potential in aluminum casting.

The Effect of Polymer Selection and Level on Shell Properties

Use & Effects on Shell Strength, Permeability & Rheology

 

A significant number of investment casting foundries add organic polymers to their backup slurry systems to make process improvements. These improvements can be in added green strength or permeability, better rheology, and thicker shells. etc. This paper will look at the relationship between polymer selection, use level, and viscosity to previously mentioned properties. The individual foundry can then use these results to optimize the polymer type, level and viscosity for their specific needs.

Enhanced Binder Systems for the Investment Casting Industy

Material Additions to Improve Performance of Colloidal Silica for Investment Casting

 

The increasingly restrictive limits on alcohol emissions has led to the development of modified colloidal silica binders – otherwise known as enhanced binders -ƒ‚ as a replacement for traditional ethyl silicate based ceramic shell systems. The first enhanced binder systems were developed for primary applications, which function to reduce surface defects such as buckle, cracking and lifting and to promote adhesion to the wax pattern. In order to achieve these goals a primary binder has different requirements to that of a backup binder, as it should have longer term stability due to its slower turnover rate and provide excellent coating characteristics.

Various types of materials such as latexes, polyvinyl alcohols, methyl cellulose, acrylic resins, etc., have been evaluated in colloidal silica to develop enhanced primary and backup binders. This has resulted in the creation of a new generation of products, such as REMASOL® ADBOND® BV and Ludox SK that have opened the door for even more research into these binder types. The enhanced primary binders have been shown to reduce typical primary type drying defects, while the backup binders have provided faster processing and higher strengths versus standard colloidal silicas.

Effect of Dilution on REMASOL® ADBOND® BV Binder

Increasing Cost Performance of this Industry Leading Binder

 

Since its market introduction in late 1992, REMASOL® ADBOND® BV binder has successfully replaced both ethyl silicate and other silica binders in foundries where fast processing times are required. Because of its good green strength, a reduction in autoclave cracking can also be realized.

Due to the variety of use conditions, additional work has been done with REMASOL ADBOND BV binder to determine the effect of dilution with respect to shell properties and improved cost performance. This paper updates that work.

Colloidal Silica in the Precision Casting Industry

Maintaining Performance in your Slurry

 

Colloidal silica is the most popular binder used in the precision casting industry today.ƒ‚ It is safe, economical, easy to use and performs well.ƒ‚ All of these desirable attributes tend to lull us into a sense of well being when we use colloidal silica.ƒ‚ We frequently forget that this work horse of the industry is sensitive and needs some attention to keep it working at its best. This paper describes colloidal silica, its properties and those things that will affect its performance.

Alumina and Zirconia Binders

Alterntaive Binders for Investment Casting

 

The paper discusses the chemical properties and bonding characteristics of new commercially available binders of aqueous colloidal alumina, monohydrate and zirconium oxide.ƒ‚ Potential applications are indicated, together with some physical property data derived from bonded refractory systems.

Investment Casting Refractory

Features and Benefits of Partially Stabilized Zirconia Crucibles for Precision Investment Casting

Investigating advantages for Vaccum Investment Casting

 

This paper prepared by Alfred Kaulius Jr. Engineering Manager at Howmet Castings, an Alcoa Business and presented by Thomas Scott, Sales & Marketing Director at Remet Corporation, at the ISIC-Tokyo 2013 conference. This paper considers the physical and chemical properties that enable partially stabilized zirconia crucibles, to be the material of choice for vacuum precision investment casting.

In the field of investment casting, the most common method of melting and preparing the alloy for casting is by use of induction heating and crucibles.  A crucible is defined as; “1. A heat-resistant vessel for melting metals or minerals.  2. A severely trying test or experience.”  In the use of crucibles for investment casting, it can be said that both definitions apply.  Not only are they used for the melting of metals for subsequent casting into the shell, the conditions to which they are repeatedly subjected are a trying test, as well.

Crucibles used for investment casting must meet a set of criteria in order to be of maximum benefit to the caster.  They must possess sufficient refractoriness for the alloy being melted.  Crucibles must have adequate thermal shock resistance to withstand the severe thermal cycling undergone through the repeated charging, melting, and casting cycle.  The melting vessel also must be compatible with the alloy being melted.  This compatibility will also be dependent on the atmosphere (or lack thereof) in which the operation is occurring.  Vacuum melt systems have different concerns than air melt systems.

Zircon

A Market Analysis of this Refractory Material

 

Zircon has historically been seen as an important material in the contemporary Precision Investment Casting Industry.ƒ‚ In this paper the authors discuss the prevailing market situation for Zircon on a world-wide basis.ƒ‚ They go on to discuss the technical nature of the material and the resulting benefits of its usage, and suggest possible substitute materials.ƒ‚ Materials such as alumino silicates, ferruginous felspars, corundums and forsterite-rich olivines are currently well known in the general foundry industry, and can, under certain circumstances, be used in the zirconƒ€™s stead.ƒ‚ The authors consider the challenges presented by these materials, and methods by which these may be resolved.

Strategies to Manage Zircon Usage in Times of Market Upheaval

Alternative Materials & Strategies to Reduce the Investment Casting Industry’s Reliance on Zircon

 

During the past several years, the zircon market has experienced volatile periods of supply and demand with correlated pricing activity.ƒ‚ These volatile periods were associated with a supply and demand imbalance that caused price spikes and material allocations, making it difficult for foundries to accurately plan production and price castings.ƒ‚ Since mid-2010, we find ourselves in another volatile period that has caused foundries to re-evaluate their processes with a goal of reducing or eliminating zircon usage.ƒ‚ By reducing dependence on zircon, foundries minimize or eliminate their exposure to this volatile market.ƒ‚ This paper will discuss testing performed on different refractory material and binder systems to identify viable and economical zircon sandƒ‚ƒ‚ and flour substitutes.ƒ‚

Reducing Zircon Sand Usage

REMASIL® 60 RG 100 A Replacement Refractory for Zircon

 

A new material, which has the potential to replace zircon sand for secondary prime dips, and possibly the first prime for some casters, has been developed. REMASIL® 60 RG100, based on a 60% alumina, alumino-silicate material, is a high mullite product which has been fired to a high temperature. It is then sized to provide the optimum match to zircon sand (the distribution is slightly coarser than zircon.) Laboratory testing (MOR, permeability and thermal expansion) was performed to determine how closely the RG100 sand performed versus zircon. The test results revealed some small differences between the two sands. The method of application (fluid bed or rainfall sander) resulted in only minor differences in the permeability or MOR results.

Ceramic Shell Cracking

Effect of Binder Selection on Drying of Recess Areas in a Shell Mold

Reducing Delays Effecting Productivity, Scrap & Rework

 

The drying of recessed areas can contribute to significant time delays in the processing of shell molds, as well as leading to rework and scrap issues. This paper will present data from various testing to evaluate the effect of different binders (polymer and non-polymer) to try to overcome this all too common problem.

Ceramic Shell and Slurry Characterisaton

Influence of Slurry Properties on Ceramic Molds

 

This paper will discuss in detail the various properties that can be quantified for a ceramic slurry and how they influence the ceramic shell.ƒ‚ƒ‚ The raw materials (colloidal silica, polymer, refractory, wetting agent, antifoam) used to make a slurry play a major role in determining the overall final ceramic shell characteristics.ƒ‚ There are many factors like silica type and level, polymer type and level, plate weight, solids loading, viscosity, flour particle size distribution, refractory type, etc that play a role on the final ceramic shell properties.ƒ‚ These factors will affect the ceramic shell with respect to strength (green, hot, fired), permeability, creep, thermal conductivity, and thermal expansion.

Ceramic Shell Production for Controlling Shell Cracking

12 Guidelines to Limit this Defect

 

This paper further considers the factors that contribute to the stresses that cause the cracking of a ceramic shell.

 It will discuss how the de-waxing process as well as the rigours of the shell building process can result in ceramic shell cracking. Maximising the green strength of the shell is then proposed as a solution to this issue, with a practical method described through:

(1) the process control of slurries and stucco

(2) Mechanics of shell building and drying.

We also include twelve guidelines to ensure optimum shell strength and therefore resist the stresses that cause cracking.

 

Avoid Shell Cracking by Controlling your Process

Reduce Likelihood of this Defect in Dewax

 

The cracking of ceramic shells, during the investment casting process is an issue well known to foundrymen. There are a number of factors that result in stress developing on a shell, causing a crack to occur, this paper will focus on the formation of a ceramic shell, in particular the process and its control.

Following this the appendices to this paper offers a guide to ensuring the selection of the correct binder and refractory for the investment casting application, as well as details on how to ensure their consistent and proper use.

Reclaimation of Investment Casting Waxes

The Reclamation of Investment Casting Waxes

Explanation of the Process & Performance of Reclaim Waxes

 

Today, the reclamation of spent investment casting wax forms an integral part of most casting wax supplier’s business activities.ƒ‚ The economic and environmental pressures existing in the current business climate have created an upswing in the volumes of wax being reprocessed and subsequently reused by investment casting foundries.

In this paper, the author considers the various wax reclamation techniques in use today.ƒ‚ By focusing on the methods used by Remet UK Ltd., he gives a detailed description of how wax returned from the foundry can be dried, cleaned and processed to yield a variety of cost effective, reclaim based products.ƒ‚ In many cases these products have performance characteristics that rival those of virgin waxes.

The paper considers the technical quality of these reclaim based products and also reflects on the steps a foundry can take to help the wax reclaimer make the best of the wax returned for reprocessing.

Investment Casting Process

Investment Casting: 5000 Years of Growth

A History of the Investment Casting Process

 

A paper written by Bob Brown and presented by Scott Lawton at the Foundry Workshop 2013.

This paper traces the history of the investment casting process, from its origins in the early bronze age, to its modern industrial applications.